aHubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University, Huangshi, P.R. China bDepartment of Chemistry, The School of Art and Science of Hubei Normal University, Huangshi, P.R. China
Abstract:
Three polypyridine ligands such as tri(2-pyridyl)methane, (2,2’-bipyridin-6-yl)di(2-pyridyl)methane and 2,6-bis[di(2-pyridyl)methyl] pyridine as well as their new iron(II) mononuclear complexes have been obtained in a one-pot synthesis. Detailed structural analyses and magnetic susceptibility measurements confirm the expected six-coordinate octahedral geometry and the metric parameters are consistent with lowspin iron(II) in the complexes.
Keywords:
polypyridine, one-pot synthesis, metal complexes, low-spin.
Citation:
H. Wang, N. Wu, J. Zheng, Ch. Zheng, D. Wang, “Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands”, Mendeleev Commun., 30:1 (2020), 100–102
Linking options:
https://www.mathnet.ru/eng/mendc1114
https://www.mathnet.ru/eng/mendc/v30/i1/p100
This publication is cited in the following 3 articles:
Shazia Parveen, Nucleic Acids, 2023, 145
Gui-Ling Wu, “The crystal structure of tris(6-methylpyridin-2-yl)phosphine selenide, C18H18N3PSe”, Zeitschrift für Kristallographie - New Crystal Structures, 237:2 (2022), 243
Gui-Ling Wu, “The crystal structure of tris(6-methylpyridin-2-yl)phosphine oxide, C18H18N3OP”, Zeitschrift für Kristallographie - New Crystal Structures, 237:4 (2022), 577
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