Abstract:
The electronic, optical, and lattice vibrational properties of CdGa2Te4 were studied experimentally using spectral ellipsometry, Raman scattering (Raman scattering) and infrared (IR) spectroscopy, as well as theoretically using the density functional theory (DFT). Eight Raman-active modes and twelve IR-active modes were detected and identified from consideration of the point group symmetry. Based on the analysis of the electronic spectrum and the density of states, the nature of the chemical bond in this semiconductor compound is determined. The theoretically calculated results are compared with the experimental data of the present work and with the results of experimental data available in the literature obtained by infrared spectroscopy and Raman scattering.
Keywords:
CdGa2Te4, Raman, IR active modes, phonon dispersion, density of states.
This work was financially supported by the Science Development Fund under the President of the Republic of Azerbaijan (grant no. EIF-BGM-3-BRFTF-2+/2017-15/02/1).
Citation:
Z. A. Jahangirli, T. G. Kerimova, I. A. Mamedova, S. A. Nabiyeva, N. A. Abdullaev, “Ab initio and experimental study of electronic, optical, and vibrational properties of CdGa2Te4”, Fizika Tverdogo Tela, 62:8 (2020), 1270–1277; Phys. Solid State, 62:8 (2020), 1426–1433
\Bibitem{JahKerMam20}
\by Z.~A.~Jahangirli, T.~G.~Kerimova, I.~A.~Mamedova, S.~A.~Nabiyeva, N.~A.~Abdullaev
\paper Ab initio and experimental study of electronic, optical, and vibrational properties of CdGa$_{2}$Te$_{4}$
\jour Fizika Tverdogo Tela
\yr 2020
\vol 62
\issue 8
\pages 1270--1277
\mathnet{http://mi.mathnet.ru/ftt8352}
\crossref{https://doi.org/10.21883/FTT.2020.08.49613.024}
\elib{https://elibrary.ru/item.asp?id=43818069}
\transl
\jour Phys. Solid State
\yr 2020
\vol 62
\issue 8
\pages 1426--1433
\crossref{https://doi.org/10.1134/S1063783420080120}
Linking options:
https://www.mathnet.ru/eng/ftt8352
https://www.mathnet.ru/eng/ftt/v62/i8/p1270
This publication is cited in the following 6 articles:
I. A. Mamedova, Z. A. Jahangirli, N. A. Abdullayev, “Electronic Properties of CdGa2S4: Ab Initio Calculations and Experimental Studies by Spectral Ellipsometry”, Phys. Solid State, 66:10 (2024), 365
A. I. Najafov, T. G. Mammadov, Kh. V. Aliguliyeva, S. Sh. Gahramanov, V. B. Aliyeva, V. N. Zverev, N. A. Abdullayev, “Low-Temperature Electrical Conductivity in Mn-Doped Bi0.9Sb0.1 Solid Solutions”, Phys. Solid State, 66:10 (2024), 399
I. A. Mamedova, Z. A. Jahangirli, S. S. Osmanova, N. A. Abdullayev, “Elastic Properties and Regularities in Frequencies of Optical Phonons of AIIBIII2CVI4 Compounds”, Phys. Solid State, 66:11 (2024), 529
Irada A. Mamedova, Zakir A. Jahangirli, Taira G. Kerimova, Nadir A. Abdullayev, “Bulk Modulus, Elastic Constants, and Force Constants of Interatomic Bonds of II–III2–VI4 Compounds”, Physica Status Solidi (b), 260:6 (2023)
Peng Wang, Yu Chu, Abudukadi Tudi, Congwei Xie, Zhihua Yang, Shilie Pan, Junjie Li, “The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material”, Advanced Science, 9:15 (2022)
Z. A. Jahangirli, R. G. Veliyev, I. A. Mamedova, Z. I. Badalova, D. A. Mamedov, N. T. Mamedov, N. A. Abdullaev, “Ab initio and experimental study of vibrational properties of TlFeS2 and TlFeSe2 crystals”, Phys. Solid State, 63:11 (2021), 1643–1649