Abstract:
The kinetic features of the thermal decomposition of HMX with metal cupferronate additives, in which the nucleophilic detachment of a proton in HMX by a phenylnitric-oxide anion-radical plays an important role, are established. The logarithms of the rate constants for the decomposition of HMX correlate with the ratio of the charge of the metal cation in the cupferronate to its radius, which indicates a different reactivity of the anion-radical owing to the polarizing effect of the cation.
Citation:
R. S. Stepanov, L. A. Kruglyakova, K. V. Pekhotin, “Kinetics and mechanism of thermal decomposition of HMX with metal cupferronate additives”, Fizika Goreniya i Vzryva, 35:3 (1999), 52–56; Combustion, Explosion and Shock Waves, 35:3 (1999), 261–265
\Bibitem{SteKruPek99}
\by R.~S.~Stepanov, L.~A.~Kruglyakova, K.~V.~Pekhotin
\paper Kinetics and mechanism of thermal decomposition of HMX with metal cupferronate additives
\jour Fizika Goreniya i Vzryva
\yr 1999
\vol 35
\issue 3
\pages 52--56
\mathnet{http://mi.mathnet.ru/fgv2332}
\elib{https://elibrary.ru/item.asp?id=14949689}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 1999
\vol 35
\issue 3
\pages 261--265
\crossref{https://doi.org/10.1007/BF02674447}
Linking options:
https://www.mathnet.ru/eng/fgv2332
https://www.mathnet.ru/eng/fgv/v35/i3/p52
This publication is cited in the following 3 articles:
Yi Yang, Lin Ding, Lin Xu, Yun-Ting Tsai, “Effect of metal chloride on thermal decomposition of nitrocellulose”, Case Studies in Thermal Engineering, 28 (2021), 101667
Alla N. Pivkina, Nikita V. Muravyev, Konstantin A. Monogarov, Igor V. Fomenkov, J. Schoonman, Energetic Nanomaterials, 2016, 193
Qi-Long Yan, Feng-Qi Zhao, Kenneth K. Kuo, Xiao-Hong Zhang, Svatopluk Zeman, Luigi T. DeLuca, “Catalytic effects of nano additives on decomposition and combustion of RDX-, HMX-, and AP-based energetic compositions”, Progress in Energy and Combustion Science, 57 (2016), 75